Intramolecular imino Diels-Alder reaction: progress toward the synthesis of uncialamycin.
نویسندگان
چکیده
We herein described an intramolecular imino Diels-Alder reaction promoted with BF(3).OEt(2)/DDQ affording substituted quinolines. Using this procedure, we prepared the chiral quinoline moiety of the uncialamycin, a new enediyne natural product.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 74 17 شماره
صفحات -
تاریخ انتشار 2009